In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Epas toxics release inventory reported that in 2007, environmental releases of hydrazine from 23 facilities totaled 16,759 lb, 14,570 lb. Hydrazine inhibits the enzyme phosphoenol pyruvate carboxykinase, thereby blocking gluconeogenesis. P272 contaminated work clothing should not be allowed out of the workplace. Hydrazine is an inorganic compound with the chemical formula n2h4. There are several types of hydrazines, including hydrazine, monomethylhydrazine mmh and. Hydrazine monohydrate 100% in hydrazine hydrate liquid. Material safety data sheet hydrazine free download as word doc.
After 96 hours, the concentration of hydrazine in guppies was about 144 ugg. Bp amoco, bp gas, power and ngl view, print and download the data sheets by simply entering the full. In the case of contact with eyes, rinse immediately with plenty of water and seek medical. Hydrazine hydrate sara 3023043112 extremely hazardous substances. Wallpapers, gaskets, cables, sport footwear, tubing, wind turbine blades, isolation panels, flotation. The another selfignitable propellant also used with 80% hydrogen peroxide was a combination of a fuel mixture that consisted of methanol mixed with calcium permanganate camno4210. Hydrazine and hydrazine sulfate national toxicology program.
Symptoms of acute shortterm exposure to high levels of hydrazine may include irritation of the eyes, nose, and throat, dizziness, headache, nausea, pulmonary edema, seizures, and coma in humans. Key players in the following businesses are confiding in arkemas hydrazine and derivatives. Safety data sheet northwest missouri state university. Hydrazine hydrate is widely used as intermediate for the synthesis of active ingredients in. Very hazardous in case of skin contact sensitizer, permeator. Niosh estimates that approximately 9000 workers are potentially exposed to hydrazine in the united states. No component of this product present at levels greater. The raschig process, the original commercial production process for hydrazine. Hydrazines are highly reactive and easily catch fire. This material does not contain any class 1 ozone depletors. However, we make no warranty of merchantibility or any other warranty, express or implied, with. Hydrazine hydrate 80% extra pure msds cas 10217524 msds.
Dilute hydrazine hydrate with water so the concentration of hydrazine is less than 5% ww. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Skin potential significant contribution to overall exposure by the cutaneous r oute. Hydrazine sulfate is the synthetic sulfate salt of hydrazine, a derivative of ammonia. Request pdf preparation of fine ni powders from nickel hydrazine complex fine nickel powders with narrow size distribution have been prepared from the. Polymorphisms in this gene are responsible for the nacetylation polymorphism in which human populations segregate into rapid, intermediate, and. Our product found applications in various industrial sectors such as water treatment, polymerization, agrochemicals, and pharmaceuticals. Hydrazine hydrate and its derivatives play a significant role in various applications. Identification of the substancemixture and of the companyundertaking. Hydrazine is highly toxic and dangerously unstable unless handled in solution as e. Hydrazine and hydrazine sulfate may be released to the environment through production, use, and waste disposal atsdr 1997, hsdb 2009. Neutralise using either 99%,which is subject to the reporting requirements of section 3 of sara title iii and 40 cfr part 373. This agent has been reported to decrease the excessive energy needs and cachexia of cancer patients. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database.
If inhaled if breathed in, move person into fresh air. The most complete free material safety data sheet msds list of. Neutralize spilled hydrazine by diluting with water to a 5% or less solution. Hydrazine hydrate h6n2o cid 24654 structure, chemical names, physical. This material does not contain any hazardous air pollutants.
Anhydrous hydrazine ah monomethyl hydrazine mmh uns dimethyl hydrazine udmh hydrogen peroxideh 2 o 2 dinitrogen tetroxiden 2 o 4 hydroxylterminated polybutadienehtpb ammonium perchlorate ap e thylamine 1anhydrous hydrazine. Hydrazine monohydrate 100% in hydrazine hydrate liquid, equivalent to 64% hydrazine synonym. It is a simple pnictogen hydride, and is a colorless and flammable liquid with an ammonialike odor. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Preparation of fine ni powders from nickel hydrazine complex. Material safety data sheet hydrazine personal protective. Liquid or spray mist may produce tissue damage particularly on mucous.
The hydrate may be produced commercially by three methods. They are highly toxic, colorless, flammable liquids with an ammonialike odor. Firstaid measures general advice show this safety data sheet to the doctor in attendance. This product contains the following ingredients for which the state of california has found to cause cancer which would require a warning under the statute. Hydrazine is used as a rocket propellant, polymerization catalyst, a blowing agent, a reducing agent, and oxygen scavenger in boiler water treatment, in the synthesis of maleic hydrazide, and in the manufacture of drugs.
These values give a bioconcentration factor of 316. H372 causes damage to organs through prolonged or repeated exposure. Causes digestive tract burns with immediate pain, swelling of the throat, convulsions, and possible coma. As a waterbased solution, hydrazine hydrate and its derivatives are supplied by arkema to be widely used as reducing agent, blowing agent, corrosion inhibitor, oxygen scavenger or intermediate of synthesis. Hydrazine, propellants, and han products online request only. Disclaimer the sds samples above are collected from the internet by chemblink and displayed here for the tutorial purpose only. Hydrazine anhydrous,monomethyl hydrazinemmh,unsdimethyl. Harmful by inhalation, contact with skin and if swallowed. Material safety data sheet hydrazine hydrate msds finar limited.
Corrosive r34 causes burns classification r202122 harmful by inhalation, contact with skin and if swallowed. Material safety data sheets from the manufacturer or distributor. Add an equal volume of 5% calcium hypochlorite aqueous solution. Cas no 7803578 corresponds to a 64% or less aqueous solution of hydrazine hsdb.
Sampling and analytical methods hydrazine occupational. Hydrazine and ndma analysis hydrazines by epa 8315 lcmsms hydrazines are most commonly known for their use in rocket fuels. Show this safety data sheet to the doctor in attendance. Hydrazine hydrate, 80% hydrazine, 51% revision date 11jul2019 4. Cas 302012 7732185 hydrazine solution 70% hydrazine water msds toxicity property. Possibly carcinogenic to humans hydrazine reproductive toxicity no data available specific target organ toxicity single exposure no data available specific target. Very hazardous in case of skin contact irritant, of ingestion.
After neutralization, transfer material to appropriate dot container for proper disposal. Buy hydrazine sulfate cas 10034932, a useful agent for the ndeacylation of various molecules, from santa cruz. The level of harm depends upon the dose, duration, and work being done. Hydrazine sulfate, more properly hydrazinium hydrogensulfate, is a salt of the cation.
Hydrazine 302012 hazard summary individuals may be exposed to hydrazine in the workplace or to small amounts in tobacco smoke. This gene encodes an enzyme that functions to both activate and deactivate arylamine and hydrazine drugs and carcinogens. No component of this product present at levels greater than or equal to 0. Hydrazine hydrazine 302012 hydrazine by diluting with water to a 5% or less solution.
In case of skin contact take off contaminated clothing and shoes immediately. Our msds database is an easy to use, do it yourself tool, and best of all. Chemtrec 8004249300 outside usa 7035273887 1216 6th ave n kent wa 98032 phone. This dossier covers the anhydrous hydrazine, ec number 2061149 and cas number 302 012.